Just downloaded and installed the new SkyDrive for Windows, It works like charm on Windows 7 and I’m about to test it on my Windows 8 tablet in just a couple of seconds, but my guess is that it is going to work there to, looks really nice/fun. Basically it will sync you SkyDrive folder between your devices, just by adding stuff in \SkyDrive makes it useable on my other devices, like a personal cloud.

Read more here, directly from the source

or skip the reading and just download it from here

or, watch this video, showing you how it works.

/mike